Semi-bridging σ-silyls as Z-type ligands-Reference-Cited by-同舟云学术

Semi-bridging σ-silyls as Z-type ligands

Published:2020 Issue:24 Volume:56 Page:3532-3535
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Frogley Benjamin J.¹²³⁴^ORCID,Hill Anthony F.¹²³⁴^ORCID,Sharma Manab¹²³⁴,Sinha Arup¹²³⁴,Ward Jas S.¹²³⁴

Affiliation:

1. Research School of Chemistry

2. Australian National University

3. Canberra

4. Australia

Abstract

The reactions of SiHPh(NCH₂PPh₂)₂C₆H₄-1,2 with zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M₂{μ-κ³-Si,P,P′-SiPh(CH₂PPh₂)₂C₆H₄}₂] (M = Ni, Pd, Pt) in which the M–M bond is unsymmetrically bridged by two σ-silyl groups.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC07763D

Reference63 articles.

1. Higher-Coordinated Molecular Silicon Compounds

2. Application of the Covalent Bond Classification Method for the Teaching of Inorganic Chemistry

3. σ-Acceptor, Z-type ligands for transition metals

4. The Sting of the Scorpion: A Metallaboratrane

5. Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes

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