Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra
4. Australia
Abstract
The reactions of [RuCl(R)(CO)(PPh3)2] (R = CHCHPh, Ph) with Na[H2B(mt)2] (mt = N-methyl-2-mercaptoimidazolyl) transiently provide [Ru(R)(CO)(PPh3){κ3-H,S,S′-H2B(mt)2}] which each evolve to the ruthenaboratrane [Ru(CO)(PPh3)2{κ3-B,S,S′-BH(mt)2}](Ru→B)8.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04813D
Reference123 articles.
1. The Sting of the Scorpion: A Metallaboratrane
2. Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}](Ru→B)8 (mt = methimazolyl, R = tBu, C6H3Me2-2,6, C6H2Me3-2,4,6)
3. Polyazolyl Chelate Chemistry. 12.1 An Unusual Mode of Coordination for the Hydrotris(methimazolyl)borato Ligand
4. Transition metals as Lewis bases: “Z-type” boron ligands and metal-to-boron dative bonding
5. σ-Acceptor, Z-type ligands for transition metals
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