Polymerisation of styrene using pincer type amine functionalized azo aromatic complexes of Co(ii) as catalysts

Author:

Goswami Bappaditya1,Khatua Manas1,Samanta Subhas2ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, West Bengal 741246, India

2. Department of Chemistry, Indian Institute of Technology Jammu, Jagti, Jammu 181221, India

Abstract

Azo-aromatic complexes of Co(ii), 1–3 have shown efficient polymerization of styrene upon activation of MMAO. The isolated polystyrenes have high Mw (32.9 to 144.0 kg mol−1) in a narrow range of Đ values (1.1–1.8) and good plastic/soft behavior.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Indian Institute of Science Education and Research Kolkata

University Grants Commission

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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