Ligand redox controlled amine dehydrogenation and imine hemilability in singlet diradical azo-aromatic Ni(<scp>ii</scp>) complexes: characterization of the electron transfer series of azo-imine complexes of Ni(<scp>ii</scp>)-Reference-Cited by-同舟云学术

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Ligand redox controlled amine dehydrogenation and imine hemilability in singlet diradical azo-aromatic Ni(ii) complexes: characterization of the electron transfer series of azo-imine complexes of Ni(ii)

Published:2024 Issue:24 Volume:53 Page:10250-10260
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Goswami Bappaditya¹^ORCID,Khatua Manas¹^ORCID,Devi Ambika²,Hans Shivali²,Chatterjee Robindo²,Samanta Subhas²^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, Nadia, West Bengal 741246, India

2. Department of Chemistry, Indian Institute of Technology Jammu, Jagti, Jammu, Jammu and Kashmir 181221, India

Abstract

Singlet diradical Ni(ii) complexes [1] and [2] of azo-amine and azo-imine ligands have shown ligand redox-induced amine dehydrogenation and imine hemilability, respectively.

Funder

Science and Engineering Research Board

University Grants Commission

Indian Institute of Science Education and Research Kolkata

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03414C

Reference54 articles.

1. Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

2. Ligands that Store and Release Electrons during Catalysis

3. Assigning Ligand Redox Levels in Complexes of 2-Aminophenolates: Structural Signatures

4. Cooperative Catalysis with First‐Row Late Transition Metals

5. Redox-active ligands in catalysis

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