Reusable manganese compounds containing pyrazole-based ligands for olefin epoxidation reactions-Reference-Cited by-同舟云学术

Reusable manganese compounds containing pyrazole-based ligands for olefin epoxidation reactions

Published:2015 Issue:40 Volume:44 Page:17529-17543
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Manrique Ester¹²³⁴⁵,Poater Albert¹²³⁴⁵,Fontrodona Xavier¹²³⁴⁵,Solà Miquel¹²³⁴⁵,Rodríguez Montserrat¹²³⁴⁵,Romero Isabel¹²³⁴⁵

Affiliation:

1. Departament de Química

2. Institut de Química Computacional i Catàlisi and Serveis Tècnics de Recerca

3. Universitat de Girona

4. E-17071 Girona

5. Spain

Abstract

New robust and effective Mn-pyrazolyl catalysts for olefin epoxidation in [bmim]PF₆ : CH₃CN, with good activity even after several reuses, are described. The cis → trans isomerization in the epoxidation of cis-β-methylstyrene is confirmed through computational calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02787J

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