Interplay of unique N⋯π pnicogen and H⋯π/H⋯O hydrogen bonding interactions in the heterodimers of nitromethane with acetylene and benzene as π-electron donors: experimental characterization at low temperatures under isolated conditions with computational corroboration-Reference-Cited by-同舟云学术

Interplay of unique N⋯π pnicogen and H⋯π/H⋯O hydrogen bonding interactions in the heterodimers of nitromethane with acetylene and benzene as π-electron donors: experimental characterization at low temperatures under isolated conditions with computational corroboration

Published:2022 Issue:46 Volume:24 Page:28411-28428
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mahapatra Nandalal¹²^ORCID,Chandra Swaroop¹²^ORCID,Ramanathan N.¹²^ORCID,Sundararajan K.¹²^ORCID

Affiliation:

1. Materials Chemistry & Metal Fuel Cycle Group, Indira Gandhi Centre for Atomic Research, Kalpakkam-603102, Tamilnadu, India

2. Indira Gandhi Centre for Atomic Research, A CI of Homi Bhabha National Institute, Kalpakkam 603102, Taminadu, India

Abstract

The dimers of nitromethane with π-electron systems as pnicogen acceptors stabilized through unique N⋯π pnicogen bonding interactions are highlighted.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP03744K

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