The versatility of lithium cation coordination modes in salts with [W(CN)6(bpy)]2− anions-Reference-Cited by-同舟云学术

The versatility of lithium cation coordination modes in salts with [W(CN)6(bpy)]2− anions

Published:2020 Issue:23 Volume:22 Page:3991-3998
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Hodorowicz Maciej¹²³⁴^ORCID,Szklarzewicz Janusz¹²³⁴^ORCID,Jurowska Anna¹²³⁴

Affiliation:

1. Jagiellonian University

2. Faculty of Chemistry

3. 30-387 Kraków

4. Poland

Abstract

Effect of the cation size (compared to Cs⁺) in Li₂[W(CN)₆(bpy)] salts on the nature of the interaction with cyanide ligands and on the crystal structure is discussed, unusual decrease of the W–W distance and increase of cell volume are observed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CE/D0CE00468E

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