Chemistry–mechanics–geometry coupling in positive electrode materials: a scale-bridging perspective for mitigating degradation in lithium-ion batteries through materials design

Author:

Santos David A.12ORCID,Rezaei Shahed3,Zhang Delin4,Luo Yuting12,Lin Binbin3ORCID,Balakrishna Ananya R.4ORCID,Xu Bai-Xiang3,Banerjee Sarbajit12ORCID

Affiliation:

1. Department of Chemistry, Texas A&M University, College Station, TX 77843, USA

2. Department of Materials Science and Engineering, Texas A&M University, College Station, TX 77843, USA

3. Institute of Materials Science, Mechanics of Functional Materials, Technische Universität Darmstadt, Otto-Berndt-Str. 3, Darmstadt 64287, Germany

4. Department of Aerospace and Mechanical Engineering, University of Southern California, Los Angeles, CA 90089, USA

Abstract

The design of next-generation positive intercalation battery cathodes will leverage chemistry—mechanics—geometry coupling to mitigate stress, unlock more accessible storage capacity, and prolong cycle life.

Funder

Deutsche Forschungsgemeinschaft

National Science Foundation

Welch Foundation

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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