N2O reduction at a dissymmetric {Cu2S}-containing mixed-valent center-Reference-Cited by-同舟云学术

N2O reduction at a dissymmetric {Cu2S}-containing mixed-valent center

Published:2014 Issue:12 Volume:5 Page:4774-4784
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Esmieu Charlène¹²³⁴⁵,Orio Maylis⁶⁷⁸⁹,Torelli Stéphane¹²³⁴⁵,Le Pape Laurent¹²³⁴⁵,Pécaut Jacques⁵¹⁰¹¹¹⁴,Lebrun Colette⁵¹⁰¹¹¹⁴,Ménage Stéphane¹²³⁴⁵

Affiliation:

1. CNRS

2. UMR 5249

3. Laboratoire de Chimie et Biologie des Métaux

4. F-38054 Grenoble Cedex 9, France

5. Univ. Grenoble Alpes

6. Laboratoire de Spectrochimie Infrarouge et Raman

7. Bâtiment C5 – UMR CNRS 8516

8. Université des Sciences et Technologies de Lille

9. F-59655 Villeneuve d'Ascq Cedex, France

10. F-38041 Grenoble Cedex 9, France

11. UMR_E 3

Abstract

Through a bio-inspired approach of the active site of the metalloenzyme nitrous oxide reductase, we isolated and characterized a dinuclear mixed-valent dicopper complex capable of N₂O reduction at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01487A

Reference58 articles.

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