Cu site differentiation in tetracopper(<scp>i</scp>) sulfide clusters enables biomimetic N<sub>2</sub>O reduction-Reference-Cited by-同舟云学术

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Cu site differentiation in tetracopper(i) sulfide clusters enables biomimetic N₂O reduction

Published:2024 Issue:34 Volume:15 Page:13668-13675
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Alayoglu Pinar¹,Rathnayaka Suresh C.¹^ORCID,Chang Tieyan²,Wang SuYin Grass²^ORCID,Chen Yu-Sheng²^ORCID,Mankad Neal P.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Illinois at Chicago, Chicago, IL 60607, USA

2. ChemMatCARS, The University of Chicago, Argonne, IL 60439, USA

Abstract

Resonant X-ray diffraction measurements were used to examine Cu site differentiation within a Cu4S cluster that distorts its geometry to activate N2O, thus mimicking the behavior of the biological CuZ active site.

Funder

Division of Chemistry

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00701H

Reference54 articles.

1. Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

2. Hydrogenases

3. Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen

4. A Cytochrome c Oxidase Model Catalyzes Oxygen to Water Reduction Under Rate-Limiting Electron Flux

5. Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase

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