Plutonium coordination and redox chemistry with the CyMe4-BTPhen polydentate N-donor extractant ligand-Reference-Cited by-同舟云学术

Plutonium coordination and redox chemistry with the CyMe4-BTPhen polydentate N-donor extractant ligand

Published:2018 Issue:89 Volume:54 Page:12582-12585
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Reilly Sean D.¹²³^ORCID,Su Jing¹²³^ORCID,Keith Jason M.¹²³,Yang Ping¹²³^ORCID,Batista Enrique R.¹²³^ORCID,Gaunt Andrew J.¹²³^ORCID,Harwood Laurence M.⁴⁵⁶⁷^ORCID,Hudson Michael J.⁴⁵⁶⁷,Lewis Frank W.⁴⁵⁶⁷⁸^ORCID,Scott Brian L.¹²³^ORCID,Sharrad Clint A.⁹¹⁰¹¹⁷^ORCID,Whittaker Daniel M.⁹¹⁰¹¹⁷^ORCID

Affiliation:

1. Los Alamos National Laboratory

2. Los Alamos

3. USA

4. Department of Chemistry

5. University of Reading

6. Whiteknights

7. UK

8. Department of Applied Sciences

9. School of Chemical Engineering and Analytical Science

10. The University of Manchester

11. Manchester

Abstract

Complexation of Pu(iv) with the actinide extractant CyMe₄-BTPhen (2,9-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-yl)-1,10-phenanthroline) was studied experimentally and by computational analysis.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC06015K

Reference13 articles.

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2. Potential Benefits and Impacts of Advanced Nuclear Fuel Cycles with Actinide Partitioning and Transmutation, NEA No. 6894, OECD, Nuclear Energy Agency (NEA), Paris, 2011

3. Radioactive waste partitioning and transmutation within advanced fuel cycles: Achievements and challenges

4. Highly Efficient Separation of Actinides from Lanthanides by a Phenanthroline-Derived Bis-triazine Ligand

5. Plutonium Loading of Prospective Grouped Actinide Extraction (GANEX) Solvent Systems based on Diglycolamide Extractants

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