Co-Crystallization of Plutonium(III) and Plutonium(IV) Diglycolamides with Pu(III) and Pu(IV) Hexanitrato Anions: A Route to Redox Variants of [PuIII,IV(DGA)3][PuIII,IV(NO3)6]x

Author:

Rotermund Brian M.1ORCID,Sperling Joseph M.12ORCID,Horne Gregory P.3,Beck Nicholas B.1,Wineinger Hannah B.12ORCID,Bai Zhuanling1ORCID,Celis-Barros Cristian2ORCID,Gomez Martinez Daniela1,Albrecht-Schönzart Thomas E.2ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, United States

2. Department of Chemistry and Nuclear Science and Engineering Center, Colorado School of Mines, Golden, Colorado 80401, United States

3. Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, Idaho 83415, United States

Funder

Basic Energy Sciences

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference68 articles.

1. Sun, A.; Zaidi, J.; Kopalek, M.; Colson, W.; Berry, R.; McGarth, G.; Shear, T.; Klein, M.; Gorski, A.; Harrison, E.; Jamison, L. Monthly Energy Review; Monthly Energy Review; OE/EIA-0035; Energy Information Administration, 2023. Vol. 351, https://www.eia.gov/totalenergy/data/monthly/pdf/mer.pdf (accessed 2023−02−01).

2. 5 Fast Facts about Spent Nuclear Fuel; Office of Nuclear Energy, 2022. https://www.energy.gov/ne/articles/5-fast-facts-about-spent-nuclear-fuel (accessed 2023−02−01).

3. Ambrosi, R.; Williams, H.; Samara-Ratna, P.; Tomkins, K.; Pulker, S.; Slade, R.; Bannister, N.; Stephenson, K.; Simpson, K.; Robbins, M.; Dimitriadou, I.; Reece, M.; Ning, H.; Chen, K.; Perkinson, M.C.; Sykes, J.; Rice, T.; Tinsley, T.; Sarsfield, M.; Vernon, D.; Crawford, T.; Stuttard, M.; Koenig, J.; Jaegle, M. Americium-241 Radioisotope Thermoelectric Generator Development for Space Applications, Brazil, 2013, Vol. 45.

4. Baron, P.; Hérès, X.; Lecomte, M.; Masson, M. Separation of the Minor Actinides: The DIAMEX-SANEX Concept, 2001.

5. Americium Recovery from Highly Active PUREX Raffinate by Solvent Extraction: The EXAm Process. A Review of 10 Years of R&D

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