Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups-Reference-Cited by-同舟云学术

Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups

Published:2018 Issue:3 Volume:54 Page:248-251
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kenzler Sebastian¹²³⁴,Schrenk Claudio¹²³⁴^ORCID,Frojd Andrew R.⁵⁶⁷⁸,Häkkinen Hannu⁹¹⁰¹¹¹²¹³^ORCID,Clayborne Andre Z.⁵⁶⁷⁸⁵^ORCID,Schnepf Andreas¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. University Tübingen

3. D-72076 Tübingen

4. Germany

5. Department of Chemistry

6. University of Missouri – Kansas City

7. Kansas City

8. USA

9. Departments of Chemistry and Physics

10. Nanoscience Center

11. University of Jyväskylä

12. Jyväskylä

13. Finland

Abstract

Reducing (Ph₃P)AuSC(SiMe₃)₃ with l-Selectride® gives the medium-sized metalloid gold cluster Au₇₀S₂₀(PPh₃)₁₂.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C7CC08014J

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