Pressure-induced non-innocence in bis(1,2-dionedioximato)Pt(ii) complexes: an experimental and theoretical study of their insulator–metal transitions-Reference-Cited by-同舟云学术

Pressure-induced non-innocence in bis(1,2-dionedioximato)Pt(ii) complexes: an experimental and theoretical study of their insulator–metal transitions

Published:2020 Issue:12 Volume:22 Page:6677-6689
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Benjamin Helen¹²³⁴,Richardson Jonathan G.¹²³⁴,Moggach Stephen A.⁵⁶⁷⁸^ORCID,Afanasjevs Sergejs⁹²³⁴,Warren Lisette¹²³⁴^ORCID,Warren Mark R.¹⁰¹¹¹²¹³⁴,Allan David R.¹⁰¹¹¹²¹³⁴^ORCID,Morrison Carole A.¹²³⁴,Kamenev Konstantin V.⁹²³⁴,Robertson Neil¹²³⁴^ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. University of Edinburgh

3. Edinburgh

4. UK

5. School of Molecular Sciences, and the Centre for Microscopy

6. Characterisation and Analysis

7. University of Western Australia

8. Australia

9. School of Engineering and Centre for Science at Extreme Conditions

10. Diamond Light Source Ltd

11. Diamond House

12. Harwell Science and Innovation Campus

13. Didcot, Oxfordshire

Abstract

Bis(1,2-dionedioximato) complexes of Pt(ii) form linear chains of metal complexes that metallise under pressure. Through high-pressure structural, computational and conductivity measurements we show the crucial role of the ligand in dictating these properties.

Funder

Diamond Light Source

Leverhulme Trust

University of Edinburgh

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06749C

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1. Possibility of Synthesizing an Organic Superconductor