Selective production of bio-based aromatics by aerobic oxidation of native soft wood lignin in tetrabutylammonium hydroxide

Author:

Hosoya Takashi1234ORCID,Yamamoto Kohei1234,Miyafuji Hisashi1234,Yamada Tatsuhiko564

Affiliation:

1. Graduate School of Life and Environmental Sciences

2. Kyoto Prefectural University

3. Kyoto 606-8522

4. Japan

5. Forestry and Forest Products Research Institute

6. Tsukuba

Abstract

Aerobic oxidation of native soft wood lignin in an aqueous solution of Bu4NOH facilitates efficient production of vanillin (4-hydroxy-3-methoxybenzaldehyde), which is one of the platform chemicals in industry.

Funder

Japan Society for the Promotion of Science

Council for Science, Technology and Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference35 articles.

1. H.-M.Chang , Oxidation , in Lignins—Occurrence, Formation, Structure and Reactions , ed. K. V. Sarkanen and C. H. Ludwig , John Wiley and Sons , NY , 1971 , pp. 433–485

2. Proposed Mechanism for the Nitrobenzene Oxidation of Lignin

3. Vanillin: Synthetic Flavoring from Spent Sulfite Liquor

4. D.Havkin-Frenkel , Vanillin , Kirk-Othmer Encyclopedia of Chemical Technology , 2018 , pp. 1–12

5. Intensified ozonolysis of lignins in a spray reactor: insights into product yields and lignin structure

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