Absolute and relative-rate measurement of the rate coefficient for reaction of perfluoro ethyl vinyl ether (C2F5OCFCF2) with OH-Reference-Cited by-同舟云学术

Absolute and relative-rate measurement of the rate coefficient for reaction of perfluoro ethyl vinyl ether (C2F5OCFCF2) with OH

Published:2018 Issue:5 Volume:20 Page:3761-3767
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Srinivasulu G.¹²³⁴,Bunkan A. J. C.¹²³⁴,Amedro D.¹²³⁴,Crowley J. N.¹²³⁴^ORCID

Affiliation:

1. Division of Atmospheric Chemistry

2. Max-Planck-Institut für Chemie

3. 55128 Mainz

4. Germany

Abstract

The rate coefficient (k₁) for the reaction of OH radicals with perfluoro ethyl vinyl ether (PEVE, C₂F₅OCFCF₂) is given by k₁(T) = 6.0 × 10⁻¹³ exp[(480 ± 38/T)] cm³ molecule⁻¹ s⁻¹.

Funder

Merck KGaA

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP08056E

Reference26 articles.

1. A. E. Feiring , in Organofluorine Chemistry: Principles and Commercial Applications , ed. R. E. Banks , B. E. Smart and J. C. Tatlow , Springer , US, Boston, MA , 1994 , pp. 339–372 10.1007/978-1-4899-1202-2_16

2. T. Hiyama and H.Yamamoto , in Organofluorine Compounds: Chemistry and Applications , ed. H. Yamamoto , Springer , Berlin, Heidelberg , 2000 , pp. 183–233 10.1007/978-3-662-04164-2_6

3. S. Ebnesajjad , in Applied Plastics Engineering Handbook , William Andrew Publishing , Oxford , 2011 , pp. 49–60 , 10.1016/B978-1-4377-3514-7.10004-2

4. Atmospheric sulfur hexafluoride: Sources, sinks and greenhouse warming

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Atmospheric oxidation of unsaturated hydrofluoroethers initiated by OH radicals;Atmospheric Environment;2023-08

2. Products and mechanism of the OH-initiated photo-oxidation of perfluoro ethyl vinyl ether, C2F5OCFCF2;Physical Chemistry Chemical Physics;2018