Products and mechanism of the OH-initiated photo-oxidation of perfluoro ethyl vinyl ether, C2F5OCFCF2-Reference-Cited by-同舟云学术

Products and mechanism of the OH-initiated photo-oxidation of perfluoro ethyl vinyl ether, C2F5OCFCF2

Published:2018 Issue:16 Volume:20 Page:11306-11316
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bunkan A. J. C.¹²³⁴,Srinivasulu G.¹²³⁴,Amedro D.¹²³⁴,Vereecken L.⁵⁶⁷⁸⁴^ORCID,Wallington T. J.⁹¹⁰¹¹¹²^ORCID,Crowley J. N.¹²³⁴^ORCID

Affiliation:

1. Division of Atmospheric Chemistry

2. Max-Planck-Institut für Chemie

3. Mainz 55128

4. Germany

5. Institute of Energy and Climate Research

6. IEK-8: Troposphere

7. Forschungszentrum Jülich GmbH

8. Jülich 52425

9. Research & Advanced Engineering

10. Ford Motor Company

11. Dearborn

12. USA

Abstract

The photo-oxidation of PEVE in 1 bar of air in the presence of NO_x results in the formation of C₂F₅OCFO, FC(O)C(O)F and CF₂O in molar yields of 0.50, 0.46 and 1.50, respectively.

Funder

Merck KGaA

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP01392F

Reference36 articles.

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