Products and mechanism of the OH-initiated photo-oxidation of perfluoro ethyl vinyl ether, C2F5OCFCF2

Author:

Bunkan A. J. C.1234,Srinivasulu G.1234,Amedro D.1234,Vereecken L.56784ORCID,Wallington T. J.9101112ORCID,Crowley J. N.1234ORCID

Affiliation:

1. Division of Atmospheric Chemistry

2. Max-Planck-Institut für Chemie

3. Mainz 55128

4. Germany

5. Institute of Energy and Climate Research

6. IEK-8: Troposphere

7. Forschungszentrum Jülich GmbH

8. Jülich 52425

9. Research & Advanced Engineering

10. Ford Motor Company

11. Dearborn

12. USA

Abstract

The photo-oxidation of PEVE in 1 bar of air in the presence of NOx results in the formation of C2F5OCFO, FC(O)C(O)F and CF2O in molar yields of 0.50, 0.46 and 1.50, respectively.

Funder

Merck KGaA

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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