Three-centre two-electron bonds from the quantum interference perspective-Reference-Cited by-同舟云学术

Three-centre two-electron bonds from the quantum interference perspective

Published:2022 Issue:26 Volume:24 Page:15958-15972
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

de Sousa David Wilian Oliveira¹^ORCID,Nascimento Marco Antonio Chaer¹^ORCID

Affiliation:

1. Instituto de Química, Universidade Federal do Rio de Janeiro, Cidade Universitária, CT Bloco A Sala 412, Rio de Janeiro, RJ 21941-909, Brazil

Abstract

The stability of chemical systems with 3c2e bonds derives from quantum interference, while other factors are always overall destabilizing. The interference energy of a 3c2e bond is about 3 times higher than that of a comparable 2c2e bond.

Funder

Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00841F

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