[2+2] Photocycloaddition in a bichromophoric dyad: photochemical concerted forward reaction following Woodward–Hoffmann rules and photoinduced stepwise reverse reaction of the ring opening <i>via</i> predissociation-Reference-Cited by-同舟云学术

[2+2] Photocycloaddition in a bichromophoric dyad: photochemical concerted forward reaction following Woodward–Hoffmann rules and photoinduced stepwise reverse reaction of the ring opening via predissociation

Published:2022 Issue:39 Volume:24 Page:24137-24145
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Budyka Mikhail F.¹^ORCID,Fedulova Julia A.¹²,Gavrishova Tatiana N.¹,Li Vitalii M.¹,Potashova Natalia I.¹,Tovstun Sergey A.¹

Affiliation:

1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka 142432, Moscow Region, Russian Federation

2. Faculty of Fundamental Physical and Chemical Engineering, Lomonosov Moscow State University, Moscow, Russian Federation

Abstract

In the styrylbenzoquinoline dyad, the [2+2] photocycloaddition reaction proceeds in concert according to the Woodward–Hoffman rules, while the reverse reaction of photoinduced cyclobutane opening proceeds stepwise by the predissociation mechanism.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02865D

Reference42 articles.

1. Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions

2. Photochemical Reactions as Key Steps in Organic Synthesis

3. Supramolecular Photochemistry as a Potential Synthetic Tool: Photocycloaddition