Poly(2-cycloalkyl-2-oxazoline)s: high melting temperature polymers solely based on Debye and Keesom van der Waals interactions

Author:

Jerca Valentin Victor12345,Lava Kathleen12345,Verbraeken Bart12345,Hoogenboom Richard12345

Affiliation:

1. Supramolecular Chemistry Group

2. Department of Organic and Macromolecular Chemistry

3. Ghent University

4. 9000 Ghent

5. Belgium

Abstract

The synthesis of new 2-cycloalkyl-2-oxazoline monomers, namely 2-cyclobutyl (cBuOx), 2-cyclopentyl (cPentOx) and 2-cyclohexyl-2-oxazoline (cHexOx) is described. Polymers thereof are semi-crystalline and reveal unexpectedly high melting transitions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference53 articles.

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5. B. Sillion , R.Mercier and D.Picq, in Synthetic Methods in Step-Growth Polymers, John Wiley & Sons, Inc., 2003, pp. 265–326, 10.1002/0471220523.ch5

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