Tuning the spin-crossover properties of FeII4L<sub>6</sub> cages <i>via</i> the interplay of coordination motif and linker modifications-Reference-Cited by-同舟云学术

Tuning the spin-crossover properties of FeII4L₆ cages via the interplay of coordination motif and linker modifications

Published:2023 Issue:36 Volume:52 Page:12789-12795
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Paschelke Tobias¹,Trumpf Eicke¹,Grantz David¹^ORCID,Pankau Malte¹,Grocholski Niclas¹^ORCID,Näther Christian²^ORCID,Sönnichsen Frank D.¹^ORCID,McConnell Anna J.¹^ORCID

Affiliation:

1. Otto Diels Institute of Organic Chemistry, Kiel University, Otto-Hahn-Platz 4, Kiel 24098, Germany

2. Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Straße 2, Kiel 24118, Germany

Abstract

The spin-crossover temperature of FeII4L6 cages in solution was tuned up to 186 K by coordination motif and linker modifications to 2,2′-pyridylbenzimidazole-based ligands.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01569F

Reference55 articles.

1. Structure:function relationships in molecular spin-crossover complexes

2. Spin-state switching in Fe(II) helicates and cages

3. Spin crossover in discrete polynuclear iron(ii) complexes

4. Spin crossover in homoleptic Fe(II) imidazolylimine complexes

5. Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration

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