Transient [3,3] Cope rearrangement of 3,3-dicyano-1,5-dienes: computational analysis and 2-step synthesis of arylcycloheptanes-Reference-Cited by-同舟云学术

Transient [3,3] Cope rearrangement of 3,3-dicyano-1,5-dienes: computational analysis and 2-step synthesis of arylcycloheptanes

Published:2018 Issue:46 Volume:9 Page:8760-8764
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Fereyduni Ehsan¹²³⁴^ORCID,Sanders Jacob N.⁵⁶⁷⁴,Gonzalez Gabriel¹²³⁴,Houk K. N.⁵⁶⁷⁴^ORCID,Grenning Alexander J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Florida

3. Gainesville

4. USA

5. Department of Chemistry and Biochemistry

6. University of California – Los Angeles

7. Los Angeles

Abstract

Unexpectedly mild [3,3] rearrangement computed transition state analysis, regio- and diastereoselecitve transformations multicomponent couplings, convergent 2-step arylcycloheptene synthesis.

Funder

University of Florida

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC03057J

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