Reply to the ‘Comment on “Revisiting π backbonding: the influence of d orbitals on metal–CO bonds and ligand red shifts”’ by G. Frenking and S. Pan, Phys. Chem. Chem. Phys., 2019, 22, DOI: 10.1039/C9CP05951B-Reference-Cited by-同舟云学术

Reply to the ‘Comment on “Revisiting π backbonding: the influence of d orbitals on metal–CO bonds and ligand red shifts”’ by G. Frenking and S. Pan, Phys. Chem. Chem. Phys., 2019, 22, DOI: 10.1039/C9CP05951B

Published:2020 Issue:9 Volume:22 Page:5380-5382
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Koch Daniel¹^ORCID,Chen Yingqian¹,Golub Pavlo¹^ORCID,Manzhos Sergei²^ORCID

Affiliation:

1. Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, Singapore, 117575, Singapore

2. Centre Énergie Matériaux Télécommunications, Institut National de la Recherche Scientifique, 1650, boulevard Lionel-Boulet, Varennes, QC J3X1S2, Canada

Abstract

We respond to the comment by Pan and Frenking with regard to our investigation on transition and alkaline earth metal d orbital influence on their bonding to carbonyl ligands to clarify misconceptions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06927E

Reference12 articles.

1. Revisiting π backbonding: the influence of d orbitals on metal–CO bonds and ligand red shifts

2. The metal–carbonyl bond in Ni(CO)4 and Fe(CO)5: A clear‐cut analysis

3. 586. Olefin co-ordination compounds. Part III. Infra-red spectra and structure: attempted preparation of acetylene complexes

4. Comment on “Observation of alkaline earth complexes M(CO) 8 (M = Ca, Sr, or Ba) that mimic transition metals”

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