Comment on “Observation of alkaline earth complexes M(CO) 8 (M = Ca, Sr, or Ba) that mimic transition metals”-Reference-Cited by-同舟云学术

Comment on “Observation of alkaline earth complexes M(CO) 8 (M = Ca, Sr, or Ba) that mimic transition metals”

Published:2019-08-09 Issue:6453 Volume:365 Page:
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Landis Clark R.¹^ORCID,Hughes Russell P.²^ORCID,Weinhold Frank¹

Affiliation:

1. Department of Chemistry, University of Wisconsin, Madison, WI 53706, USA.

2. Department of Chemistry, Dartmouth College, Hanover, NH 03755, USA.

Abstract

Wu et al . (Reports, 31 August 2018, p. 912) claim that recently characterized octacarbonyls of Ca, Sr, and Ba mimic the classical Dewar-Chatt-Duncanson bonding motif of transition metals. This claim, which contradicts known chemistry and computed electron density distributions, originates in the assumption of a flawed reference state for energy decomposition analyses.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference11 articles.

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