Phosphine and phosphine oxide groups in metal–organic frameworks detected by P K-edge XAS-Reference-Cited by-同舟云学术

Phosphine and phosphine oxide groups in metal–organic frameworks detected by P K-edge XAS

Published:2015 Issue:5 Volume:17 Page:3326-3331
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Morel F. L.¹²³⁴,Pin S.⁵⁶⁷⁴,Huthwelker T.⁵⁶⁷⁴,Ranocchiari M.⁵⁶⁷⁴,van Bokhoven J. A.¹²³⁴⁵

Affiliation:

1. Department of Chemistry and Applied Biosciences

2. ETH Zürich

3. 8093 Zürich

4. Switzerland

5. Laboratory for Catalysis and Sustainable Chemistry

6. Paul Scherrer Institut

7. 5232 Villigen

Abstract

The synthesis of phosphine-functionalized metal–organic frameworks frequently leads to the formation of different phosphorus environment inside the framework. We used P K-edge X-ray absorption spectroscopy to quantify phosphine and phosphine oxide groups inside two frameworks with MIL-101 topology.

Funder

Eidgenössische Technische Hochschule Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05151C

Reference34 articles.

1. Selective gas adsorption and separation in metal–organic frameworks

2. Metal–Organic Frameworks in Biomedicine

3. Biomedical Applications of Metal Organic Frameworks