Affiliation:
1. Division of Arts and Sciences Texas A&M University Qatar Education City Doha Qatar
2. Department of Chemistry Texas A&M University College Station TX 77843-3255 USA
3. School of Materials Science and Engineering China University of Petroleum (East China) Qingdao 266580 P. R. China
Abstract
AbstractPhosphine‐functionalized metal‐organic frameworks (P‐MOFs) as an emerging class of coordination polymers, have provided novel opportunities for the development of heterogeneous catalysts. Yet, compared with the ubiquitous phosphine systems in homogeneous catalysis, heterogenization of phosphines in MOFs is still at its early stage. In this Minireview, we summarize the synthetic strategies, characterization and catalytic reactions based on the P‐MOFs reported in literature. In particular, various catalytic reactions are discussed in detail in terms of phosphine ligand structure‐function relationship, including the potential obstacles for future development. Finally, we discuss the possible solutions, including new types of reactions and techniques as the perspectives for the development of P‐MOF catalysts, highlighting the opportunities and challenges.
Funder
Qatar National Research Fund
Welch Foundation
National Natural Science Foundation of China
Subject
General Chemistry,Catalysis
Cited by
5 articles.
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