Tri- and hexanuclear heterometallic Ni(ii)–M(ii) (M = Ca, Sr and Ba) bis(salamo)-type complexes: synthesis, structure and fluorescence properties

Author:

Dong Xiu-Yan1234,Li Xiao-Yan1234,Liu Ling-Zhi1234,Zhang Han1234,Ding Yu-Jie5674,Dong Wen-Kui1234ORCID

Affiliation:

1. School of Chemical and Biological Engineering

2. Lanzhou Jiaotong University

3. Lanzhou

4. PR China

5. School of Biological & Chemical Engineering

6. Anhui Polytechnic University

7. Wuhu 241000

Abstract

Tri- and hexanuclear Ni(ii)–M(ii) (M = Ca, Sr and Ba) complexes have been synthesized and characterized structurally. Fluorescence titration experiments show that the coordinating capabilities in the central O6 site are in the order of Ca(ii) > Sr(ii) > Ba(ii).

Funder

National Natural Science Foundation of China

Lanzhou Jiaotong University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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