Quadruple bridged-carbonate supported dodecanuclear [Ni<sub>8</sub>Ca<sub>4</sub>] coordination cluster-Reference-Cited by-同舟云学术

Quadruple bridged-carbonate supported dodecanuclear [Ni₈Ca₄] coordination cluster

Published:2024 Issue:7 Volume:48 Page:3239-3246
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kajal ¹,Vinayak Richa¹,Gómez-García Carlos J.²^ORCID,Benmansour Samia²^ORCID,Nayek Hari Pada¹^ORCID

Affiliation:

1. Department of Chemistry & Chemical Biology, Indian Institute of Technology (Indian school of Mines), Dhanbad-826004, Jharkhand, India

2. Departamento de Química Inorgánica. Universidad de Valencia. C/Dr Moliner 50. 46100 Burjasot, Valencia, Spain

Abstract

A reaction of a polydentate Schiff-base ligand with NiII, CaII and Na2CO3 in dimethylformamide yields a Ni8Ca4 coordination wheel, which is the largest reported Ni–Ca coordination cluster and shows alternating ferro- and antiferromagnetic Ni···Ni interactions.

Funder

Council of Scientific and Industrial Research, India

Ministerio de Ciencia e Innovación

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D3NJ05217F

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