Cu-Catalyzed intermolecular [3 + 3] annulation involving oxidative activation of an unreactive C(sp3)–H bond: access to pyrimidine derivatives from amidines and ketones
Author:
Affiliation:
1. Key Laboratory of Functional Molecular Engineering of Guangdong Province
2. School of Chemistry and Chemical Engineering
3. South China University of Technology
4. Guangzhou 510640
5. China
Abstract
An efficient approach to pyrimidines through a copper-catalyzed oxidative unreactive C(sp3)–H bond and intermolecular [3 + 3] annulation of amidines and ketones is described.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00842A
Reference54 articles.
1. A Facile FeCl3/I2-Catalyzed Aerobic Oxidative Coupling Reaction: Synthesis of Tetrasubstituted Imidazoles from Amidines and Chalcones
2. CH Functionalization/CN Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines
3. Ligand-Free Copper-Catalyzed Arylation of Amidines
4. Base-Mediated Syntheses of Di- and Trisubstituted Imidazoles from Amidine Hydrochlorides and Bromoacetylenes
5. Access to Pyridyl-Substituted 1,3,5-Triazines from 4H-Pyrido[1,3]oxazin-4-ones via a Cyclocondensation Process
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