Cu-Catalyzed intermolecular [3 + 3] annulation involving oxidative activation of an unreactive C(sp3)–H bond: access to pyrimidine derivatives from amidines and ketones-Reference-Cited by-同舟云学术

Cu-Catalyzed intermolecular [3 + 3] annulation involving oxidative activation of an unreactive C(sp3)–H bond: access to pyrimidine derivatives from amidines and ketones

Published:2017 Issue:6 Volume:4 Page:1107-1111
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Guo Wei¹²³⁴⁵^ORCID,Liu Dongqing¹²³⁴⁵,Liao Jianhua¹²³⁴⁵,Ji Fanghua¹²³⁴⁵,Wu Wanqing¹²³⁴⁵,Jiang Huanfeng¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Functional Molecular Engineering of Guangdong Province

2. School of Chemistry and Chemical Engineering

3. South China University of Technology

4. Guangzhou 510640

5. China

Abstract

An efficient approach to pyrimidines through a copper-catalyzed oxidative unreactive C(sp³)–H bond and intermolecular [3 + 3] annulation of amidines and ketones is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00842A

Reference54 articles.

1. A Facile FeCl3/I2-Catalyzed Aerobic Oxidative Coupling Reaction: Synthesis of Tetrasubstituted Imidazoles from Amidines and Chalcones

2. CH Functionalization/CN Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines

3. Ligand-Free Copper-Catalyzed Arylation of Amidines

4. Base-Mediated Syntheses of Di- and Trisubstituted Imidazoles from Amidine Hydrochlorides and Bromoacetylenes

5. Access to Pyridyl-Substituted 1,3,5-Triazines from 4H-Pyrido[1,3]oxazin-4-ones via a Cyclocondensation Process

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