Intramolecular C–H oxidative addition to iridium(i) triggered by trimethyl phosphite in N,N′-diphosphanesilanediamine complexes
Author:
Affiliation:
1. Centro Universitario de la Defensa
2. ES-50090 Zaragoza
3. Spain
4. Departamento de Química Inorgánica
5. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)
6. Universidad de Zaragoza-CSIC
7. ES-50009 Zaragoza
Abstract
The intramolecular C–H oxidative addition in the IrI(κ2P,P′-SiNP) moiety is triggered by trimethyl phosphite and yields the IrIIIH(κ3C,P,P′-{SiNP-H}) scaffold.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02886H
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2. Ethylene Tri- and Tetramerization: a Steric Parameter Selectivity Switch from X-ray Crystallography and Computational Analysis
3. Protonation of metal–metal bonds in coordinatively unsaturated diruthenium cores
4. Preparation, Characterization, and Reactivity of Dinitrogen Molybdenum Complexes with Bis(diphenylphosphino)amine Derivative Ligands that Form a Unique 4-Membered P–N–P Chelate Ring
5. Exploring Small Bite-Angle Ligands for the Rhodium-Catalyzed Intermolecular Hydroacylation of β-S-Substituted Aldehydes with 1-Octene and 1-Octyne
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1. Reactivity of Ir(i)-aminophosphane platforms towards oxidants;Dalton Transactions;2023
2. Synthesis and reactivity of an iridium complex based on a tridentate aminophosphano ligand;Dalton Transactions;2022
3. Accessing δ-B–H Coordinated Complexes of Rh(I) and Ir(I) Using Mono- and Dihydroboranes: Cooperative Stabilization by a Phosphoramidate Coligand;Organometallics;2016-12-28
4. En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond;Dalton Transactions;2016
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