Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects

Author:

Bilyachenko Alexey N.12345ORCID,Korlyukov Alexander A.12367ORCID,Vologzhanina Anna V.123ORCID,Khrustalev Victor N.453ORCID,Kulakova Alena N.123,Long Jérôme89101112ORCID,Larionova Joulia89101112ORCID,Guari Yannick89101112ORCID,Dronova Marina S.123,Tsareva Ulyana S.123,Dorovatovskii Pavel V.13143,Shubina Elena S.123ORCID,Levitsky Mikhail M.123

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences

2. 119991 Moscow

3. Russia

4. Peoples’ Friendship University of Russia (RUDN University)

5. 117198 Moscow

6. Pirogov Russian National Research Medical University

7. 117997 Moscow

8. Institut Charles Gerhardt

9. UMR5253

10. Ingénierie Moléculaire et Nano-Objets

11. Université de Montpellier

12. Univ. Montpellier

13. National Research Center “Kurchatov Institute”

14. 123098 Moscow

Abstract

The ability of the polynuclear cage metallasilsesquioxane [(PhSiO1.5)12(CuO)4(NaO0.5)4(n-BuOH)8] with a globular structure to act as a stable building block of hybrid materials with respect to the substitution of sodium cations and terminal butanol molecules was confirmed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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