Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)

Author:

Batten Stuart R.1,Champness Neil R.2,Chen Xiao-Ming3,Garcia-Martinez Javier4,Kitagawa Susumu5,Öhrström Lars6,O’Keeffe Michael7,Paik Suh Myunghyun8,Reedijk Jan9

Affiliation:

1. 1School of Chemistry, Monash University, Victoria 3800, Australia

2. 2School of Chemistry, University of Nottingham, Nottingham NG7 2RD, UK

3. 3School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, PR China, 510275

4. 4Universidad de Alicante, Departamento de Química Inorgánica, Carretera San Vicente del Raspeig s/n, E-03690 Alicante, Spain

5. 5Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan

6. 6Department of Chemical and Biological Engineering, Physical Chemistry, Chalmers University of Technology, SE-412 96 Göteborg, Sweden

7. 7Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287, USA

8. 8Department of Chemistry, Seoul National University, Seoul 151-747, South Korea

9. 9Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands

Abstract

A set of terms, definitions, and recommendations is provided for use in the classification of coordination polymers, networks, and metal–organic frameworks (MOFs). A hierarchical terminology is recommended in which the most general term is coordination polymer. Coordination networks are a subset of coordination polymers and MOFs a further subset of coordination networks. One of the criteria an MOF needs to fulfill is that it contains potential voids, but no physical measurements of porosity or other properties are demanded per se. The use of topology and topology descriptors to enhance the description of crystal structures of MOFs and 3D-coordination polymers is furthermore strongly recommended.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference18 articles.

1. ar u;Keeffe;Chem Res,1782

2. Long;Yaghi Chem Soc Rev,1039

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