The effects of symmetry and rigidity on non-adiabatic dynamics in tertiary amines: a time-resolved photoelectron velocity-map imaging study of the cage-amine ABCO-Reference-Cited by-同舟云学术

The effects of symmetry and rigidity on non-adiabatic dynamics in tertiary amines: a time-resolved photoelectron velocity-map imaging study of the cage-amine ABCO

Published:2016 Issue:14 Volume:18 Page:9715-9723
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Klein Liv B.¹²³⁴,Morsing Thorbjørn J.¹²³⁴,Livingstone Ruth A.⁵⁶⁷⁸,Townsend Dave⁹¹⁰¹¹¹²¹³,Sølling Theis I.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Copenhagen

3. DK-2100 Copenhagen Ø

4. Denmark

5. Center for Free-Electron Laser Science

6. DESY

7. 22607 Hamburg

8. Germany

9. Institute of Photonics & Quantum Sciences

10. Heriot-Watt University

11. Edinburgh

12. UK

13. Institute of Chemical Sciences

Abstract

The non-adiabatic relaxation dynamics of the tertiary cage-amine azabicyclo[2.2.2]octane (ABCO) have been investigated following 3p Rydberg excitation at 201 nm using femtosecond time-resolved photoelectron imaging.

Funder

Natur og Univers, Det Frie Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP07910A

Reference49 articles.

1. The role of novel Rydberg-valence behaviour in the non-adiabatic dynamics of tertiary aliphatic amines

2. Rydberg Fingerprint Spectroscopy: A New Spectroscopic Tool with Local and Global Structural Sensitivity

3. Electronic Structure of Cage Amines: Absorption Spectra of Triethylenediamine and Quinuclidine