Photochemical carbon–sulfur bond cleavage in thioethers mediated <i>via</i> excited state Rydberg-to-valence evolution-Reference-Cited by-同舟云学术

Photochemical carbon–sulfur bond cleavage in thioethers mediated via excited state Rydberg-to-valence evolution

Published:2022 Issue:48 Volume:24 Page:29423-29436
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kotsina Nikoleta¹^ORCID,Jackson Sebastian L.¹^ORCID,Malcomson Thomas²^ORCID,Paterson Martin J.³^ORCID,Townsend Dave¹³^ORCID

Affiliation:

1. Institute of Photonics & Quantum Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK

2. Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

3. Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK

Abstract

Time-resolved photoelectron imaging and supporting quantum chemistry calculations provide detailed new insight into the excess energy redistribution dynamics operating in thioethers following ultraviolet excitation.

Funder

Heriot-Watt University

Leverhulme Trust

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP04789F

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