Photochemical carbon–sulfur bond cleavage in thioethers mediated via excited state Rydberg-to-valence evolution

Author:

Kotsina Nikoleta1ORCID,Jackson Sebastian L.1ORCID,Malcomson Thomas2ORCID,Paterson Martin J.3ORCID,Townsend Dave13ORCID

Affiliation:

1. Institute of Photonics & Quantum Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK

2. Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

3. Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK

Abstract

Time-resolved photoelectron imaging and supporting quantum chemistry calculations provide detailed new insight into the excess energy redistribution dynamics operating in thioethers following ultraviolet excitation.

Funder

Heriot-Watt University

Leverhulme Trust

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Mapping extended reaction coordinates in photochemical dynamics;Journal of Molecular Spectroscopy;2023-05

2. Photodissociation dynamics of tetrahydrofuran at 193 nm;Physical Chemistry Chemical Physics;2023

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