Revealing the role of excited state proton transfer (ESPT) in excited state hydrogen transfer (ESHT): systematic study in phenol

Revealing the role of excited state proton transfer (ESPT) in excited state hydrogen transfer (ESHT): systematic study in phenol–(NH3)n clusters

Published:2021 Issue:11 Volume:12 Page:3836-3856
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jouvet Christophe¹²³⁴⁵^ORCID,Miyazaki Mitsuhiko⁶⁷⁸⁹¹⁰^ORCID,Fujii Masaaki¹¹¹²¹³¹⁴¹⁰^ORCID

Affiliation:

1. CNRS

2. Aix Marseille Université

3. Physique des Interactions Ioniques et Moleculaires (PIIM)

4. UMR 7345

5. 13397 Marseille Cedex

6. Natural Science Division

7. Faculty of Core Research

8. Ochanomizu University

9. Tokyo 112-8610

10. Japan

11. World Research Hub Initiatives

12. Institute of Innovative Research

13. Tokyo Institute of Technology

14. Yokohama 226-8503

Abstract

A general model of excited state hydrogen transfer (ESHT) which unifies ESHT and the excited state proton transfer (ESPT) is presented from experimental and theoretical works on phenol–(NH₃)n. The hidden role of ESPT is revealed.

Funder

Japan Society for the Promotion of Science

Tokyo Institute of Technology

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06877B

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