Dynamic Role of the Intramolecular Hydrogen Bonding in the S<sub>1</sub> State Relaxation Dynamics Revealed by the Direct Measurement of the Mode-Dependent Internal Conversion Rate of 2-Chlorophenol and 2-Chlorothiophenol-Reference-Cited by-同舟云学术

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Dynamic Role of the Intramolecular Hydrogen Bonding in the S₁ State Relaxation Dynamics Revealed by the Direct Measurement of the Mode-Dependent Internal Conversion Rate of 2-Chlorophenol and 2-Chlorothiophenol

Published:2023-09-15 Issue:38 Volume:14 Page:8428-8436
ISSN:1948-7185
Container-title:The Journal of Physical Chemistry Letters
language:en
Short-container-title:J. Phys. Chem. Lett.

Author:

Kim Junggil¹,Woo Kyung Chul¹^ORCID,Kang Minseok¹,Kim Sang Kyu¹^ORCID

Affiliation:

1. Department of Chemistry, KAIST, Daejeon 34141, Republic of Korea

Funder

National Research Foundation of Korea

Ministry of Trade, Industry and Energy

Publisher

American Chemical Society (ACS)

Subject

General Materials Science,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c02208

Reference89 articles.

1. Excited-state hydrogen detachment and hydrogen transfer driven by repulsive 1πσ* states: A new paradigm for nonradiative decay in aromatic biomolecules

2. πσ* excited states in molecular photochemistry

3. The role of πσ* states in the photochemistry of heteroaromatic biomolecules and their subunits: insights from gas-phase femtosecond spectroscopy

4. Structure and dynamic role of conical intersections in the πσ*-mediated photodissociation reactions

5. Tunneling dynamics dictated by the multidimensional conical intersection seam in the πσ*‐mediated photochemistry of heteroaromatic molecules

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