Dual stereocontrolled alkylation of aldehydes with polystyrene-supported nickel complexes derived from α-amino amides

Author:

Escorihuela Jorge1234,Altava Belén1234,Burguete M. Isabel1234,Luis Santiago V.1234

Affiliation:

1. Departamento de Química Inorgánica y Orgánica

2. Universitat Jaume I

3. E-12071 Castellón

4. Spain

Abstract

Nickel(ii) complexes derived from α-amino amide ligands anchored to gel-type and monolithic polymers act as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference84 articles.

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3. F. D. Klingler , in Asymmetric Catalysis on Industrial Scale: Challenges, Approaches and Solutions, ed. H. U. Blaser and H.-J. Federsel, WILEY-VCH Verlag GmbH & Co.KGaA, Weinheim, 2010, pp. 171–185

4. D. V. De Vos , I. F. J.Vankelecom and P. A.Jacobs, Chiral Catalyst Immobilization and Recycling, WILEY-VCH: Verlag GmbH, 2007

5. K. Ding and Y.Uozumi, Handbook of Asymmetric Heterogeneous Catalysis, Wiley-VCH: Verlag GmbH, 2008

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