Mechanistic implications of the enantioselective addition of alkylzinc reagents to aldehydes catalyzed by nickel complexes with α-amino amide ligands
Author:
Affiliation:
1. Departamento de Química Inorgánica y Orgánica
2. Universitat Jaume I
3. 12071 Castellón de la Plana
4. Spain
5. Unitat de Química Física
6. Departament de Química
7. Edifici Cn. Universitat Autònoma de Barcelona
8. Barcelona
Abstract
The enantioselective alkylation of aldehydes catalysed by nickel(ii)-complexes derived from α-amino amides was studied by means of density functional theory (DFT) and ONIOM (B3LYP:UFF) calculations.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB01878E
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