Mechanistic implications of the enantioselective addition of alkylzinc reagents to aldehydes catalyzed by nickel complexes with α-amino amide ligands-Reference-Cited by-同舟云学术

Mechanistic implications of the enantioselective addition of alkylzinc reagents to aldehydes catalyzed by nickel complexes with α-amino amide ligands

Published:2016 Issue:47 Volume:14 Page:11125-11136
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Escorihuela Jorge¹²³⁴^ORCID,Burguete M. Isabel¹²³⁴,Ujaque Gregori⁵⁶⁷⁸⁴,Lledós Agustí⁵⁶⁷⁸⁴^ORCID,Luis Santiago V.¹²³⁴

Affiliation:

1. Departamento de Química Inorgánica y Orgánica

2. Universitat Jaume I

3. 12071 Castellón de la Plana

4. Spain

5. Unitat de Química Física

6. Departament de Química

7. Edifici Cn. Universitat Autònoma de Barcelona

8. Barcelona

Abstract

The enantioselective alkylation of aldehydes catalysed by nickel(ii)-complexes derived from α-amino amides was studied by means of density functional theory (DFT) and ONIOM (B3LYP:UFF) calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB01878E

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