Selective hydrogenation of acetophenone with supported Pd and Rh catalysts in water, organic solvents, and CO2-dissolved expanded liquids

Author:

Fujita Shin-ichiro12345,Onodera Yuichi12345,Yoshida Hiroshi12345,Arai Masahiko12345

Affiliation:

1. Division of Applied Chemistry

2. Faculty of Engineering

3. Hokkaido University

4. Sapporo 060-8628

5. Japan

Abstract

Solvent effects appear to depend on supports but not on metals in the absence of CO2. Different CO2 effects appear among the catalysts. Water is a better solvent for the reaction for all catalysts under neat and expanded solvent conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference36 articles.

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2. G. V. Smith and F.Notheisz, Heterogeneous Catalysis in Organic Chemistry, Academic, London, 1995

3. Catalysis: An Integrated Approach, ed. R. A. van Santen, P. W. N. M. van Leeuwen, J. A. Moulijn and B. A. Averill, Elsevier, Amsterdam, 2nd edn, 1999

4. R. A. Sheldon and H.van Bekkum, Fine Chemicals through Heterogeneous Catalysis, Wiley-VCH, Weinheim, 2001

5. Solvent effects in heterogeneous selective hydrogenation of acetophenone: differences between Rh/C and Rh/Al2O3 catalysts and the superiority of water as a functional solvent

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