Solvent effects in heterogeneous selective hydrogenation of acetophenone: differences between Rh/C and Rh/Al2O3 catalysts and the superiority of water as a functional solvent-Reference-Cited by-同舟云学术

Solvent effects in heterogeneous selective hydrogenation of acetophenone: differences between Rh/C and Rh/Al2O3 catalysts and the superiority of water as a functional solvent

Published:2015 Issue:3 Volume:17 Page:1877-1883
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Yoshida Hiroshi¹²³⁴⁵,Onodera Yuichi¹²³⁴⁵,Fujita Shin-ichiro¹²³⁴⁵,Kawamori Hiroki¹²³⁴⁵,Arai Masahiko¹²³⁴⁵

Affiliation:

1. Division of Chemical Process Engineering

2. Faculty of Engineering

3. Hokkaido University

4. Sapporo 060-8628

5. Japan

Abstract

Strong solvent effects appear in different manners for Rh/C and Rh/Al₂O₃ catalysts. However, these give the highest yields of phenylethanol in the presence of water.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/GC/C4GC02211D

Reference20 articles.

1. C. Reichardt , Solvents and Solvent Effects in Organic Chemistry, Wiley-VCH, Weinheim, 3rd edn, 2003

2. Reactions of C−H Bonds in Water

3. Organic Synthesis “On Water”

4. Water: Nature’s Reaction Enforcer—Comparative Effects for Organic Synthesis “In-Water” and “On-Water”

5. P. N. Rylander , Hydrogenation Methods, Academic Press, London, 1985

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