Hydrogen bonding to metals as a probe for an inverted ligand field-Reference-Cited by-同舟云学术

Hydrogen bonding to metals as a probe for an inverted ligand field

Published:2021 Issue:16 Volume:50 Page:5465-5472
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pérez-Bitrián Alberto¹²³⁴^ORCID,Baya Miguel¹²³⁴^ORCID,Casas José M.¹²³⁴^ORCID,Martín Antonio¹²³⁴^ORCID,Menjón Babil¹²³⁴^ORCID

Affiliation:

1. Instituto de Síntesis Química y Catálisis Homogénea (iSQCH)

2. CSIC–Universidad de Zaragoza

3. Zaragoza

4. Spain

Abstract

The M⋯HO axial interaction in the isoleptic and isoelectronic square-planar compounds [(CF₃)₃Pt(hq)]⁻ and (CF₃)₃Au(hq) turns from attractive (M = Pt) to repulsive (M = Au), evidencing ligand-field inversion when going from Pt to Au.

Funder

Ministerio de Educación, Cultura y Deporte

Ministerio de Ciencia e Innovación

Gobierno de Aragón

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00597A

Reference85 articles.

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4. G. R. Desiraju and T.Steiner , The Weak Hydrogen Bond , Oxford University Press , 1999 , sect. 3.5.1, pp. 271–277

5. Non-conventional hydrogen bonds

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