Tuning the hyperconjugative aromaticity in Au(iii)-substituted indoliums

Author:

Zhao Yu12345,Zeng Jie12345,Zhu Jun12345ORCID

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM)

2. Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry

3. College of Chemistry and Chemical Engineering

4. Xiamen University

5. Xiamen 361005

Abstract

The hyperconjugative aromaticity in Au(iii)-substituted indoliums could be regained or enhanced by cistrans isomerization or ligand effects.

Funder

National Natural Science Foundation of China

National Program for Support of Top-notch Young Professionals

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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