Aromaticity enhancement of cyclopentadiene in piperidine derivatives: a DFT study on combination of the anomeric effect and Schleyer hyperconjugative aromaticity-Reference-Cited by-同舟云学术

Aromaticity enhancement of cyclopentadiene in piperidine derivatives: a DFT study on combination of the anomeric effect and Schleyer hyperconjugative aromaticity

Published:2023 Issue:12 Volume:47 Page:5863-5874
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Taghiboroujerdi Mohammad¹,Mirjafary Zohreh¹,Saeidian Hamid²^ORCID

Affiliation:

1. Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran

2. Department of Science, Payame Noor University (PNU), PO Box: 19395-4697, Tehran, Iran

Abstract

The cyclopentadiene (Cp) hyperconjugative aromaticity on anomeric carbon of piperidines was studied using DFT method. The aromaticity indices showed that Cp has considerably enhanced cyclic conjugation in comparison with unsubstituted Cp.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ00337J

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