Divergent synthesis of polysubstituted cyclopropanes and β-silyoxy imidates via switchable additions of N-tert-butanesulfinylimidates to acylsilanes-Reference-Cited by-同舟云学术

Divergent synthesis of polysubstituted cyclopropanes and β-silyoxy imidates via switchable additions of N-tert-butanesulfinylimidates to acylsilanes

Published:2019 Issue:26 Volume:55 Page:3777-3780
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tang Fan¹²³⁴⁵,Ma Peng-Ju¹²³⁴⁵,Yao Yun⁶⁷⁸⁵,Xu Yan-Jun¹²³⁴⁵,Lu Chong-Dao¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Plant Resources and Chemistry of Arid Zones

2. Xinjiang Technical Institute of Physics & Chemistry

3. Chinese Academy of Sciences

4. Urumqi 830011

5. China

6. School of Chemical Science and Technology

7. Yunnan University

8. Kunming 650091

Abstract

A switchable addition of N-tert-butanesulfinylimidates to acylsilanes leads to divergent synthesis of polysubstituted cyclopropanes and β-silyloxy imidates.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC00963A

Reference49 articles.

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5. Regiospecific and diastereoselective aldol reaction of chiral N-sulfinyl metalloenamines with α,β-unsaturated trifluoromethyl ketones: Asymmetric synthesis of tertiary trifluoromethyl allylic carbinols

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