Wavelength-dependent rearrangements of an α-dione chromophore: a chemical pearl in a bis(hypersilyl) oyster-Reference-Cited by-同舟云学术

Wavelength-dependent rearrangements of an α-dione chromophore: a chemical pearl in a bis(hypersilyl) oyster

Published:2024 Issue:12 Volume:15 Page:4427-4433
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Glotz Gabriel¹,Drusgala Manfred²,Hamm Florian¹,Fischer Roland C.²^ORCID,Došlić Nađa³,Kelterer Anne-Marie¹^ORCID,Gescheidt Georg¹^ORCID,Haas Michael²^ORCID

Affiliation:

1. Institute of Physical and Theoretical Chemistry, Graz University of Technology, Stremayrgasse 9/II, 8010 Graz, Austria

2. Institute of Inorganic Chemistry, Graz University of Technology, Stremayrgasse 9/IV, 8010 Graz, Austria

3. Department of Physical Chemistry, Ruđer Bošković Institute, Bijenička 54, Zagreb, Croatia

Abstract

Herein the authors report on the synthesis and photochemistry of a symmetric bissilyl-dione. This compound reveals a wavelength dependent and moreover highly selective photochemistry, which is based on the bissilyl substitution of the dione.

Funder

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00064A

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