Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases-Reference-Cited by-同舟云学术

Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases

Published:2015 Issue:21 Volume:44 Page:9847-9859
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Jisheng¹²³⁴⁵,Wang Yujuan¹²³⁴⁵,Luo Nengchao¹²³⁴⁵,Chen Zhuqi¹²³⁴⁵,Wu Kangbing¹²³⁴⁵,Yin Guochuan¹²³⁴⁵

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Huazhong University of Science and Technology

3. Key Laboratory for Large-Format Battery Materials and System

4. Ministry of Education

5. Wuhan 430074

Abstract

Interaction of Zn²⁺with Fe(TPA)Cl₃can trigger ET from amine to iron(iii) generating a substrate radical which traps dioxygen to produce alkylperoxyl, thus initiating catalytic oxidation, resembling lipoxygenase-like dioxygen activation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00804B

Reference129 articles.

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