Shift of the reduction potential of nickel(ii) Schiff base complexes in the presence of redox innocent metal ions

Author:

Bhunia Pradip1,Gomila Rosa M.2ORCID,Frontera Antonio2ORCID,Ghosh Ashutosh1ORCID

Affiliation:

1. Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata-700 009, India

2. Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

Abstract

Apart from the Lewis acidity of redox-inactive metal ions,  the local electric field, especially for bivalent metal ions, and the size of the chelate ring formed by the ligand can also impact the  reduction potential of NI(ii/i) pair.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

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