Shift of the reduction potential of nickel(<scp>ii</scp>) Schiff base complexes in the presence of redox innocent metal ions-Reference-Cited by-同舟云学术

Shift of the reduction potential of nickel(ii) Schiff base complexes in the presence of redox innocent metal ions

Published:2024 Issue:29 Volume:53 Page:12316-12330
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bhunia Pradip¹,Gomila Rosa M.²^ORCID,Frontera Antonio²^ORCID,Ghosh Ashutosh¹^ORCID

Affiliation:

1. Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata-700 009, India

2. Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

Abstract

Apart from the Lewis acidity of redox-inactive metal ions, the local electric field, especially for bivalent metal ions, and the size of the chelate ring formed by the ligand can also impact the reduction potential of NI(ii/i) pair.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00953C

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4. Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways

5. Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes