Kinetic stabilization allows structural analysis of a benzoborirene-Reference-Cited by-同舟云学术

Kinetic stabilization allows structural analysis of a benzoborirene

Published:2022 Issue:17 Volume:58 Page:2818-2821
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sindlinger Marvin¹^ORCID,Ströbele Markus²^ORCID,Maichle-Mössmer Cäcilia²^ORCID,Bettinger Holger F.¹^ORCID

Affiliation:

1. Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

2. Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

Abstract

The successful synthesis and first structural characterization by single crystal X-ray crystallography of a highly strained benzoborirene motif, as well as its reactivity towards selected electrophiles and nucleophiles are reported.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC06588B

Reference73 articles.

1. The Concept of Strain in Organic Chemistry

2. Unusual ring systems in organic chemistry

3. Strain-release amination

4. Cleavage of Carbon–Carbon σ-Bonds of Four-Membered Rings

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