Avenue to novel <i>o</i>-carboranyl boron compounds – reactivity study of <i>o</i>-carborane-fused aminoborirane towards organic azides-Reference-Cited by-同舟云学术

Avenue to novel o-carboranyl boron compounds – reactivity study of o-carborane-fused aminoborirane towards organic azides

Published:2024 Issue:13 Volume:15 Page:4839-4845
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Junyi¹²,Xiang Libo³⁴,Liu Xiaocui¹,Matler Alexander³⁴,Lin Zhenyang²^ORCID,Ye Qing³⁴^ORCID

Affiliation:

1. Department of Chemistry, Southern University of Science and Technology, 518055 Shenzhen, P. R. China

2. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong

3. Institute of Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

4. Institute for Sustainable Chemistry& Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

Abstract

A range of novel o-carboranyl substituted boron compounds have been synthesized through reactions between an o-carborane-fused aminoborirane and various organic azides. The reaction selectivity and mechanisms were studied using DFT calculations.

Funder

Deutsche Forschungsgemeinschaft

Hong Kong University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00489B

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