Towards the surface hydroxyl species in CeO2 nanoparticles

Author:

Plakhova Tatiana V.1234ORCID,Romanchuk Anna Yu.1234ORCID,Butorin Sergei M.56789ORCID,Konyukhova Anastasia D.1234ORCID,Egorov Alexander V.1234,Shiryaev Andrey A.123410ORCID,Baranchikov Alexander E.123411ORCID,Dorovatovskii Pavel V.1234ORCID,Huthwelker Thomas13141516ORCID,Gerber Evgeny1718192021ORCID,Bauters Stephen1718192021ORCID,Sozarukova Madina M.112234ORCID,Scheinost Andreas C.1718192021ORCID,Ivanov Vladimir K.123411ORCID,Kalmykov Stepan N.123410ORCID,Kvashnina Kristina O.1718192021ORCID

Affiliation:

1. Lomonosov Moscow State University

2. Department of Chemistry

3. Moscow

4. Russia

5. Molecular and Condensed Matter Physics

6. Department of Physics and Astronomy

7. Uppsala University

8. Uppsala

9. Sweden

10. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science

11. Kurnakov Institute of General and Inorganic Chemistry

12. National Research Centre “Kurchatov Institute”

13. Paul Scherrer Institute

14. Swiss Light Source

15. Villigen

16. The Switzerland

17. The Rossendorf Beamline at ESRF – The European Synchrotron

18. 38043 Grenoble Cedex 9

19. France

20. Helmholtz Zentrum Dresden-Rossendorf (HZDR)

21. Institute of Resource Ecology

22. Russian Academy of Sciences

Abstract

X-ray absorption experiments at Ce L3 and M5 edges and theoretical calculations demonstrate that in addition to the nanoceria charge stability, the formation of hydroxyl groups at the surface affects the chemical performance of nanomaterials.

Funder

H2020 European Research Council

Russian Foundation for Basic Research

Russian Science Foundation

Vetenskapsrådet

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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